Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution

نویسندگان

  • Clare Bakewell
  • Andrew J. P. White
  • Mark R. Crimmin
چکیده

Addition of the carbon-fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.

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عنوان ژورنال:

دوره 138  شماره 

صفحات  -

تاریخ انتشار 2016